Head to Blade's Edge Mountains and get all the quests you can. You need 86 to complete the achievement so it will take you awhile. The following is a list of spots to grab some quests:

Neutral Quest Spots

1. Evergrove - (61,39) Northeast of the Circle of Blood
2. Circle of Blood / Ogri'la - (53,44) North of Thunderlord Stronghold

Alliance Quest Spots

1. Bladespire Hold - (44,51) North of Sylvanaar
2. Sylvanaar - (37,64) West of Thunderlord Stronghold
3. Toshley's Station - (60,68) West of Death's Door

Horde Quest Spots

1. Bladespire Hold - (44,51) North of Sylvanaar
2. Bloodmaul Ravine - (45,78) Southwest of Thunderlord Stronghold
3. Mok'Nathal Village - (74,61) East of Death's Door
4. Thunderlord Stronghold - (51,58) South of Circle of Blood

Below is a list of commonly missed quests.

1. Felsworn Mask. Dropped by Fel Corrupter found at (71,35). This is a 9 part quest chain.
2. Meeting Note. Dropped by Wyrmcult Hewer and Poacher's found at (60,36). This is a 5 part quest chain.
3. Orb of the Grishna, Dropped by Grishna Falconwing, Scorncrow, Harbinger, and Matriarch. They can be found at (40,20). This is a 3 part quest chain.
4. Gorgrom's Favor(Alliance). Dropped by Dorgok who is found at (55,25).
5. Killing the Crawlers (Both) given by Grunt Grahk (Horde) found at (53,96) or Sentinel Moonwhisper (Alliance) found at 32,91 in the tunnel that connects Zangarmarsh and Blade's Edge Mountains.
6. They Stole Me Hookah and Me Brews! (Horde) this is a nice 4 part quest chain. Find the quest giver T'chali the Witch Doctor at (45,72).