Cheap and quick way to complete this Achievement would be to head to the town centers and look for the main faction Tabards. The new tabards they have out allow you to gain 100% faction towards each city you wear. 

1. Buy city tabard.

2. Queue for random dungeon.

3. Rinse and repeat until Exalted is earned.

Darnassus

1. Do all of the quests that grant Darnassus reputation.
2. Locate Raedon Duskstriker in the Craftsmen's Terrace of Darnassus. Now pick up and complete A Donation of Wool and complete all of his donation quests, there will be 4 and each give 350 reputation. Once you have completed all of Raedon's quests you will now be able to get the Additional Runecloth quest, rewarding 75 reputation per turn in.

Exodar

1. Do all of the quests that grant Exodar reputation.
2. Locate Dugiru in the Traders Tier of Exodar. Now pick up and complete A Donation of Wool and complete all of his donation quests, there will be 4 and each give 350 reputation. Once you have completed all of Dugiru's quests you will now be able to get the Additional Runecloth quest, rewarding 75 reputation per turn in.

Gnomeregan Exiles

1. This is by far the hardest Alliance faction to gain reputation with, lots of runecloth turn ins.
2. Do all of the quests that grant Gnomeregan Exiles reputation.
3. Locate Bubulo Acerbus in Tinker Town of Ironforge. Now pick up and complete A Donation of Wool and complete all of his donation quests, there will be 4 and each give 350 reputation. Once you have completed all of Bubulo's quests you will now be able to get the Additional Runecloth quest, rewarding 75 reputation per turn in.

Ironforge

1. Do all of the quests that grant Ironforge reputation.
2. Locate Mistina Steelshield in Ironforge. Now pick up and complete A Donation of Wool and complete all of his donation quests, there will be 4 and each give 350 reputation. Once you have completed all of Mistina's quests you will now be able to get the Additional Runecloth quest, rewarding 75 reputation per turn in.

Stormwind

1. Do all of the quests that grant Gnomeregan Exiles reputation.
2. Locate Clavicus Knavingham in the Mage Quarter of Stormwind. Now pick up and complete A Donation of Wool and complete all of his donation quests, there will be 4 and each give 350 reputation. Once you have completed all of Clavicus's quests you will now be able to get the Additional Runecloth quest, rewarding 75 reputation per turn in.